APTN National NewsDocumentary makers go far and wide to show their films.But that’s not the case for one Inuk film maker.For years, she would only show her film to Indigenous audiences.Monday in Montreal, she relented, but only with certain conditions.APTN’s Tom Fennario email@example.com
Climate change negotiations at a United Nations conference in Nairobi are progressing toward decisions on key issues that include adaptation, financial mechanisms, deforestation, technology transfer and capacity building, officials there said today.Yvo de Boer, Executive Secretary of the UN Framework Convention on Climate Change (UNFCCC), said countries, in discussions on reducing future emissions, were focusing on a workplan for subsequent negotiations. They have agreed that the next step should focus on “mitigation potential,” or “what can we actually do to reduce emissions of industrialized countries.” Concluding the first week of talks, the 189 parties to the Climate Change Convention are also discussing various ways to move forward on future commitments for industrialized countries to reduce emissions after the Kyoto Protocol, which covers a commitment period of 2008 to 2012. “The Convention is telling you that you need to avoid dangerous anthropogenic interference with climate systems,” Mr. de Boer said. “In order to achieve that goal you need to take action. The question is how can you take that action most effectively at the national level and through cooperation at the international level.”Mr. de Boer said a proposal from the Russian Federation that would make it possible for any country in the future to make voluntary commitments to reduce emissions was the subject of serious discussions and disagreements, and that countries were deciding how to deal with it. Progress has been on an international programme to reduce emissions in countries with economies in transition. The programme, known as Joint Implementation, provides a new market-based mechanism to promote emission reducing projects through cooperation between industrialized countries and countries with economies in transition, was officially launched on 26 October. Another mechanism, the Clean Development Mechanism, already exists to promote development in developing countries through the trading of emission rights.Daniela Stoycheva, Chair of the Joint Implementation Supervisory Committee that oversees Joint Implementation, said four projects had been received so far, in Bulgaria, Russia and Ukraine, and that 125 were expected in 2007. She said countries that buy emission rights included Austria, Denmark, Italy, Japan, Netherlands and Spain.Mr. de Boer said there is a very large potential for Joint Implementation projects in countries with economies in transition because emissions can be reduced to a lower cost there. read more
NEW YORK — Right-hander Parker Bridwell was claimed off waivers from the Los Angeles Angels by the New York Yankees, who opened a roster spot by designating infielder Ronald Torreyes for assignment.Bridwell, 27, was 10-3 with a 3.64 ERA in 20 starts and one relief appearance for the Angels in 2017, then missed much of this year because of right elbow inflammation. He was 1-0 with a 17.55 ERA in one start and four relief appearances over 6 2/3 innings for the Angels and 1-1 with an 8.68 ERA at Triple-A Salt Lake.Bridwell is 11-3 with a 4.60 ERA for Baltimore and the Angels in 28 games over three seasons. He was designated for assignment last week by the Angels.The 26-year-old Torreyes was among the most popular players in the Yankees clubhouse, a 5-foot-8 backup often hoisted into the air by teammates to high-five 6-foot-7 Aaron Judge. Torreyes hit .292 with 36 RBIs in 315 at-bats over 108 games in 2017, but spent much of this year at Triple-A Scranton/Wilkes-Barre and batted .280 with seven RBIs in 100 at-bats over 41 games for the Yankees.New York announced the moves on Monday.___More AP MLB: https://apnews.com/MLB and https://twitter.com/AP_SportsThe Associated Press read more
The Mets, who already leaned heavily on their pitchers — only the Yankees and Athletics got a higher share of their total WAR from pitchers in 2016 — are in line to become even more pitcher-reliant this offseason, as several of their fielders enter the free-agent market. Sure, ageless wonder Bartolo Colón has departed for the Atlanta Braves, but New York’s biggest free-agent questions were always going to involve position players.One of those questions was answered Monday, when Neil Walker accepted the Mets’ qualifying offer, saving New York the headache of trying to fill a hole at the keystone. But they still have to account for the possible loss of outfielder Yoenis Céspedes, who’s projected for 3.0 WAR in 2017. Given the gap in the lineup that losing his bat would leave, there’s a case to be made that the Mets should just pony up whatever it takes to re-sign Céspedes. But “whatever it takes” will probably amount to quite a bit of money in this year’s weak free-agent class, and there are other, cheaper options available: Dexter Fowler (2.3), Carlos Gómez (2.1) and Ian Desmond (1.5) stand out. Look for the Mets to go that way.Speaking of Gómez and Desmond, they’re part of what could be a mass exodus from Texas, as they join first baseman Mitch Moreland (0.8), designated hitter Carlos Beltrán (0.4), and starting pitchers Derek Holland (1.8) and Colby Lewis (1.1) in free agency. Sorting it all out is going to be a tough winter assignment for Rangers GM Jon Daniels.Signing Mike Napoli (0.9) for another Texas tour of duty or going slightly up-market for Edwin Encarnación (2.3) would go a long way toward replacing Moreland and Beltran (both of whom could, of course, come back), and it’s not unreasonable to expect either Desmond or Gómez, both of whom can play center field, to return. The bigger problem is in the rotation, where Holland and Lewis had contributed nearly 30 percent of Texas’s rotational WAR since 2010. The Rangers don’t have any obvious internal options to step into those spots, and the free-agent market looks thin aside from Rich Hill (2.9), who’ll probably get better options elsewhere. A trade may be in the offing.North of the border, the Blue Jays have just over nine wins coming off their roster, headlined by the aforementioned Encarnación, plus longtime star José Bautista (2.9), and the recently departed — also to Atlanta! — R.A. Dickey (2.0), among others. Some of Dickey’s production can be replaced with relative ease, but signing Kendrys Morales (0.9) and Cuban superstar Lourdes Gurriel Jr.4Who wasn’t projected by Fangraphs. significantly lowered the odds that either Encarnación or Bautista will return to the Blue Jays next year. Of the two, Bautista is the most likely to come back — at 36, he doesn’t have much upside left, he had a down season last year, and he is clearly comfortable in Toronto. No matter what happens, this offseason has already done much to reshape the Jays’ talented roster.Finally, the Los Angeles Dodgers have a league-high 12.5 projected wins rolling off their roster, mainly in Justin Turner (3.7), Rich Hill (2.9), Josh Reddick (2.1), and Kenley Jansen (1.5). Jansen, a lights-out reliever, will probably get the most press this offseason, but L.A.’s shake-ups in the field — which have already included trading away Howie Kendrick and Carlos Ruiz — will be the most interesting to watch.The Dodgers seem likely to retain at least one of their four big free agents, but they probably won’t keep all four. That’ll mean some tough choices: L.A. can probably survive Reddick leaving, but there aren’t many enticing options available if Turner ends up packing his bags. A trade with the Tampa Bay Rays for Evan Longoria has been bandied about by the Twitter cognoscenti, but that’ll cost L.A. a haul in terms of both prospects and dollars, if the Rays’ past dealmaking habits — and complicated relationship with the current Dodgers’ front office — is any indication. The Dodgers have enough smarts, money and talent to contend for years to come; they’ll need all three to get this offseason right.There are limits to thinking about the offseason purely in terms of projected free-agent WAR, to be sure. For one thing, projection systems — even the very best — have flaws. For another, teams often have a better sense of their own departing free agents’ skill sets — and likelihood of performance decline — than anyone else, inside or outside the industry, so they may be basing their free-agency decisions on information that projection systems don’t have. And, more broadly, trying to evaluate whole offseasons through the lens of free agency alone misses the extreme impact that trades — and normal player development and growth — will have on the state of the league in 2017. But knowing how the projections treat every club’s outgoing free agents can give us a better sense of how the offseason will play out for each team, whether they spent 2016 at the top of the heap or staring up from the basement. In Major League Baseball, just about the only thing harder than getting to the top is staying there. In that respect, this year is no different than any other. Each of the four teams projected to lose the most production in free agency this winter — the Los Angeles Dodgers, the Toronto Blue Jays, the Texas Rangers and the New York Mets — were playoff teams in 2016, and each of them must now move with speed and smarts to shore up their position among baseball’s elite.To some extent, it makes sense for top free-agent talent to be clustered in top teams: While the average turnover rate for MLB rosters is somewhere around 30 percent, playoff teams tend to have — big shocker here — better players than non-playoff teams, so 30 percent of a playoff team’s roster1Even if turnover is distributed unevenly among players with different amounts of service time, as this Ben Lindbergh piece suggests it generally is. is likely to be a more capable bunch than 30 percent of, say, the Atlanta Braves’ roster.2Bartolo Colon’s recent arrival notwithstanding.Still, by combining a list of major-league free agents compiled by Spotrac with Fangraphs’ Steamer projections for each player’s wins above replacement next year,3We downloaded Fangraphs’ list of players and their projected WAR on November 12, 2016. Numbers are accurate as of that date. Some players may not appear in Fangraphs’ data set, and we excluded the 24 free agents who have not played in the big leagues in the last two years and therefore were not projected by Fangraphs’ system. it’s possible to get a rough sense of which teams will have their work cut out for them on the free-agency front. These numbers were calculated going into free agency, so they don’t reflect the first few signings of the offseason. They do, however, accurately reflect the wide range of challenges teams faced at the outset of the main period of the offseason. read more
She explained: “There isn’t enough education and it should start really quite young, explaining that there is a range and that – just as we all look different in our faces – we all look different down there, and that’s OK.”The doctor thinks labiaplasty should only be performed on girls who have a medical abnormality.In 2015-16, more than 200 girls under 18 had labiaplasty on the NHS, and over 150 of the girls were under 15.”I find it very hard to believe there are 150 girls with a medical abnormality which means they needed an operation on their labia,” she said.The majority are performed by private surgeons on women over the age of 18.Despite the industry being criticised for fueling insecurities, plastic surgeon Miles Berry defended the surgery.He told the BBC: “It can change people fundamentally, the feelings they have about themselves, their confidence and self-esteem.”I have seen patients aged between 16 and 21 who have never had a boyfriend because they are so concerned about this.” Ms de Zulueta said it is the fault of pornography and social media. She said she is yet to see a young girl who needs the operation.Paquita de Zulueta, a GP for more than 30 years, told the BBC that it is only in the past few years young women have been coming to her with concerns about the shape of their privates.She said: “I’m seeing young girls around 11, 12, 13 thinking there’s something wrong with their vulva – that they’re the wrong shape, the wrong size, and really expressing almost disgust.” Unbelievable that any doctor would perform this surgery on a young girl! What a shame that young girls feel this way about their bodies.— Stephanie (@StephanieIvey13) July 3, 2017 Want the best of The Telegraph direct to your email and WhatsApp? Sign up to our free twice-daily Front Page newsletter and new audio briefings. The teenage girls seeking genital surgery – including one who was just 9 years old https://t.co/eVcTEzvDw2 #VictoriaLIVE— Victoria Derbyshire (@vicderbyshire) July 3, 2017 Girls as young as nine are reportedly seeking surgery on their private parts because of insecurities stemming from adult content such as pornography, according to leading doctors.Naomi Crouch is a gynaecology specialist and she told the BBC about the worrying trend.She said: “Girls will sometimes come out with comments like, ‘I just hate it, I just want it removed,’ and for a girl to feel that way about any part of her body – especially a part that’s intimate – is very upsetting.”The doctor also said she was worried that GPs are referring young girls for unneeded labiaplasty – an operation where the lips of the vagina are shortened or reshaped. read more
Yes.No.Don’t know.Vote Don’t know. (455) No. (3662) Poll Results: THE GAA HAS reached a deal with residents near Croke Park which means that no more than three concerts a year will be held at the inner-city Dublin stadium.It comes following a long running dispute that intensified when the stadium agreed to hold eight concerts over the course of this summer, going back on earlier commitments to cap it a three.Some residents say the concerts hamper their quality of life while others say it goes with the territory of living near an 80,000-seater stadium.Today’s poll, Would you live beside a large stadium? Yes. (2589)
If you thought Grumpy Cat hated everything, you’ve never met Pompous Albert. He’s the newest member of the commercial realm’s character lineup, joining the likes of Grumpy Cat with his genuine dislike for most things. Pompous Albert is firmly part of Honda’s camp, and he really gives ol’ Tardar Sauce a run for her money.Albert the cat doesn’t like anything, really. That’s why he chooses Honda’s Authorized Service Center if he needs something done to his vehicle. And that’s why he’s starring in a Honda commercial, natch. He doesn’t like ‘80s parties, yoga, or anything to do with “meh” vehicles. You can’t really blame him. Who likes most of those things, sans the ‘80s parties?The commercial itself isn’t very long, but it does a good job of introducing the cat (which isn’t a prop or a plush toy, by the way) and a surreal set of vignettes. No one likes a terrible mechanic. Word.Heck out the catchy new commercial and see if you don’t instantly become a fan of adorable little Albert. I don’t know about you, but I’m absolutely here for another unique cat. The likes of Grumpy Cat, Lil’ Bub and now Pompous Albert give me life. Nine of them, to be exact. And they’re so darn cute. What do you think about little Albert and this quirky new Honda commercial? Maybe Albert just needs a hug to save him from all those unpaid internships after all? Or just a nice brushing.Let us know what you like about Geek by taking our survey. ‘Chonky’ 26-Pound Cat Goes Viral Online, Receives Potential AdoptersFirefighters Respond to Fire Alarm at Shelter, Discover Cat Triggered It Stay on target read more
Beaches reconstruction delayed, delivery mix up at airport Recommended for you Related Items:beaches, qatar royalty Survey shows TCI beaches keep visitors coming Facebook Twitter Google+LinkedInPinterestWhatsApp Hurricane Irma causes major damage and destruction in TCI Facebook Twitter Google+LinkedInPinterestWhatsAppProvidenciales, 10 Aug 2015 – Qatar royalty is residing with a large and lavish contingent at Beaches Resort Villages and Spa. Originally, Magnetic Media was informed that it was the actual emir of Qatar who brought in a 200 person delegation including wife and seven children, but we now correct that it is brother of the emir who is enjoying a vacation on the World’s #1 Island Destination: Providenciales. High security alert is on at Beaches, which is the World’s Leading six-star family all inclusive, and with the TCI Police Force. read more
(Jim Dau / Alaska Department of Fish and Game)One of the most exclusive animal hunts in the United States happens on a small corner of Alaska on the Bering Sea. On two subarctic islands live herds of a large, prehistoric mammal that roamed the tundra during the last Ice Age. Muskoxen are prized for their fatty, flavorful meat and soft, warm fur. Every year, thousands of people apply online for less than 200 winter permits to hunt them in Alaska. Or, for the truly devoted, you can travel to Bethel to sign up in person.It’s 7:30 a.m. outside the Alaska Department of Fish and Game office in Bethel. It’s dark, above freezing, and a line of vehicles, each holding a couple of men, wait outside. A white jeep has its window down.“I’m Adam London,” says the man sitting in the driver’s seat, holding a paper coffee cup. “This is my first winter here in Bethel. My buddy Kent over here convinced me that it’d be a good idea to come camp out and try to get a muskox permit.”Kent Wong is sitting in the passenger seat. He’s from Anchorage, and for more than 20 years he has applied annually for a muskox permit in the state lottery; he has never gotten one. So when London moved to Bethel, he saw his chance. The two men had been in the parking lot since the prior afternoon, leaving only, as London said, “for a quick potty break and getting some coffee.”In a large, blue van next to them lounge two hunters from Fairbanks. The van belongs to the Bethel Evangelical Covenant Church, where London works as a pastor. He offered the van to the hunters to sleep in so they wouldn’t have to pitch a tent in the parking lot.“It’s an outreach [ministry],” London joked.At 7:45 a.m. an ADF&G biologist shows up; the permits open at 8 a.m. Unlocking the door, the biologist announces that the hunters can start chasing him inside. But there’s no need to chase him. The men have already agreed on their order and written it on a ripped-out sheet of notebook paper taped to the door. The paper is referred to as both an “honor system” and “a gentlemen’s agreement.” According to the long-time hunters, this agreement has never been broken.At the Bethel office are two muskox permits for Nelson Island and 10 permits for Nunivak Island.The name on the top of the list, for the only bull permit, is 18-year-old Avery Hoffman of Bethel, who had not left the parking lot in 24 hours.“I have done this before,” Hoffman explained, wearing glasses instead of his usual contacts after a night of sleeping in his 1997 Ford Explorer. “The last time I waited in line, I was in line for about three days. My teacher would come and bring me my school work, and he would pick it up at the end of the day and bring it back to the school.”Hoffman has hunted muskox on Nelson Island for years. The young, though experienced, hunter shared pointers with the out-of-towners from Anchorage and Fairbanks as they waited.“When you’re out there you mainly look for black, because they’re black. You look for black things on the white ground,” Hoffman described. “Look on the hills. Sometimes they’re on the peaks up there where the wind is, and we take our binoculars and we glass across. And we ask the locals around there to have a general idea where the muskox are.”A few minutes before 8 a.m., another experienced hunter walks in. Tim Bee of Bethel says that he has hunted muskox on Nunivak Island at least 24 times. And for the first time, Bee didn’t need to camp overnight to get his permit. Competition has gone down, and no one from outside Alaska even came this year. Last year, a hunter from New Jersey camped in the parking lot for a week. Of the 12 open slots, five are still available when Bee arrives.“The cost of going out to Nunivak is pretty expensive,” Bee explained. “It’s a $500 to $600 ticket. And just the logistics of getting across the island on a snowmachine; you have to rent a snowmachine. You can’t bring your own out there.”Then, without any announcement, ADF&G biologist Patrick Jones begins to hand out the permits. Jones knows all the names by sight. Either he knows them from Bethel, or he met them in the parking lot the day before, so calling out names isn’t necessary.Jones says that the Yukon-Kuskokwim Delta mainland could open a muskox hunt in as little as 10 years if the current population of the animals continues to grow.The Nelson and Nunivak Island muskox permits became available in Bethel on January 15, 2019.A total of 133 Nunivak Island muskox permits were given out this year: 63 draw bull permits online. 10 registration cow permits in Bethel. 60 registration cow permits in Mekoryuk.A total of 50 Nelson Island muskox permits were given out: two bull and two cow draw permits online. One bull and one cow registration permits in Bethel. Twenty-two cows and 22 bull registration permits in Newtok. read more
Popular on Variety The three-on-three hoops action of Big3 — the basketball league co-founded by Ice Cube that features former NBA stars in fast-paced, half-court games — will be coming to Facebook later this month.Fox Sports signed a deal with the social-media platform to stream one Big3 game per week live during the 2018 season exclusively on Facebook, free to anyone in the world to watch. The games on Facebook will lead in to three additional games, which will air exclusively on Fox or FS1 (and simulcast live in the Fox Sports app) during the regular season and playoffs.The pact tips off with the Big3 season opener in Houston on June 22, available on the Big3 on Fox page (facebook.com/big3onfox) for the first nine weeks of the season. In addition to getting exclusive live access to nine games this summer, Facebook will host highlight packages and game recaps for all 37 games, including the championship in Brooklyn on Aug. 24. ×Actors Reveal Their Favorite Disney PrincessesSeveral actors, like Daisy Ridley, Awkwafina, Jeff Goldblum and Gina Rodriguez, reveal their favorite Disney princesses. Rapunzel, Mulan, Ariel,Tiana, Sleeping Beauty and Jasmine all got some love from the Disney stars.More VideosVolume 0%Press shift question mark to access a list of keyboard shortcutsKeyboard Shortcutsplay/pauseincrease volumedecrease volumeseek forwardsseek backwardstoggle captionstoggle fullscreenmute/unmuteseek to %SPACE↑↓→←cfm0-9Next UpJennifer Lopez Shares How She Became a Mogul04:350.5x1x1.25×1.5x2xLive00:0002:1502:15 Big3 launched its inaugural season last year, with a format in which the first team to 50 points wins along with other novel features like a four-point line (30 feet from the net). The league was founded by producer-actor-rapper Ice Cube and his manager, entertainment industry exec Jeff Kwatinetz.“Given that our fans had an average age of more than 10 years younger than typical basketball fans, we want to provide digital viewing experiences so they can engage with our league in a format that best suits their viewing preferences,” Big3 co-CEO Kwatinetz said in a statement.“Basketball conversation doesn’t have an off-season on our platform, so we’re excited for these social-first broadcasts to amplify this engagement over the summer,” added Devi Mahadevia, Facebook’s live sports programming lead for North America.The first Big3 game to stream on Facebook (June 22) features a matchup between Rashard Lewis’ 3 Headed Monsters and Mike Bibby’s Ghost Ballers. That will be followed by FS1’s broadcast of Chauncey Billups’ Killer 3’s and Dermarr Johnson’s 3’s Company; Corey Maggette’s Power and Brian Scalabrine’s Ball Hogs; and Kenyon Martin’s Trilogy and Jermaine O’Neal’s Tri-State.The league’s players include Amar’e Stoudemire, Baron Davis, Kenyon Martin, Stephen Jackson, Chauncey Billups, Metta World Peace, and Nate Robinson, along with well-known coaches like Julius “Dr. J” Erving, Gary Payton, Nancy Lieberman and George “The Iceman” Gervin.Pictured above: Trilogy’s Al Harrington (r.) shoots with Killer 3’s Reggie Evans defending during the Big3 league’s debut at the Barclays Center in New York in June 2017. read more
More information: Chemical mapping of a single molecule by plasmon-enhanced Raman scattering, Nature 498, 82–86 (06 June 2013) doi:10.1038/nature12151AbstractVisualizing individual molecules with chemical recognition is a longstanding target in catalysis, molecular nanotechnology and biotechnology. Molecular vibrations provide a valuable ‘fingerprint’ for such identification. Vibrational spectroscopy based on tip-enhanced Raman scattering allows us to access the spectral signals of molecular species very efficiently via the strong localized plasmonic fields produced at the tip apex. However, the best spatial resolution of the tip-enhanced Raman scattering imaging is still limited to 3−15 nanometres, which is not adequate for resolving a single molecule chemically. Here we demonstrate Raman spectral imaging with spatial resolution below one nanometre, resolving the inner structure and surface configuration of a single molecule. This is achieved by spectrally matching the resonance of the nanocavity plasmon to the molecular vibronic transitions, particularly the downward transition responsible for the emission of Raman photons. This matching is made possible by the extremely precise tuning capability provided by scanning tunnelling microscopy. Experimental evidence suggests that the highly confined and broadband nature of the nanocavity plasmon field in the tunnelling gap is essential for ultrahigh-resolution imaging through the generation of an efficient double-resonance enhancement for both Raman excitation and Raman emission. Our technique not only allows for chemical imaging at the single-molecule level, but also offers a new way to study the optical processes and photochemistry of a single molecule. When a weak light beam of green color illuminates the molecule alone, the molecule is visible but lack of structural details (owing to the optical diffraction limit). However, when positioned under a tip, a much more intense and localized red-shifted light, produced by the plasmonic field, is acting on the molecule. The combination of both beams projects the vibrational fingerprints of the molecule into the emitting beam, chemically resolving the inner structure of the molecule with sub-nm resolution. Credit: Dong Xie and Rongting Zhou. Raman spectroscopy is where chemists shine a laser on a small group of molecules and then measure the light as it’s bounced back. The photons from the light source cause the molecules to vibrate and to interact with the bonds that hold molecules together causing a shift in their frequency—the scattering that results is unique for each type of molecule and thus allows for the method to be used as a means of identifying molecule types. Citation: Researchers use Raman spectroscopy and STM to allow chemical mapping of molecules to 1nm resolution (2013, June 6) retrieved 18 August 2019 from https://phys.org/news/2013-06-ramen-spectroscopy-stm-chemical-molecules.html Journal information: Nature Owing to the optical diffraction limit, a single porphyrin molecule cannot be resolved by conventional optical imaging with a green laser alone. However, when the molecule is positioned under a tip, a much more intense and localized red-shifted light, produced by the plasmonic field, is acting on the molecule. The combination of both beams projects the vibrational fingerprints of the molecule into the emitting beam, chemically resolving the inner structure of the molecule with sub-nm resolution. This document is subject to copyright. Apart from any fair dealing for the purpose of private study or research, no part may be reproduced without the written permission. The content is provided for information purposes only. © 2013 Phys.org Top left: experimental map of an isolated porphyrin molecule for a given vibration frequency revealing the four-lobe pattern. Bottom left: theoretical calculation of the same molecular vibration showing its fingerprint. On the right: molecular structure of the porphyrin used in the experiment. Credit: Guoyan Wang and Yan Liang. Research team devises better method for mapping orbitals of molecules Left: Schematic diagram of tunneling-controlled tip-enhanced Raman scattering (TERS) in a confocal-type side-illumination configuration, in which Vb is the sample bias and It is the tunneling current. A laser light is focused into the nanocavity defined by the scanning tunneling microscope (STM) tip and substrate. The strong local plasmonic field generated by the incident laser causes the enhancement of Raman scattering from the single molecule underneath the tip. Top right: TERS spectrum acquired on the lobe; Bottom right: TERS map for the vibrational mode at about 817 cm-1 and corresponding line profile. Credit: Zhenchao Dong The researchers note their technique is still in the very early stages of development—thus far they’ve only been able to use it on one molecule—a ring-shaped porphyrin. The process they note, is difficult and can take weeks or months carry out making its application impractical at this point for general research efforts. Also it only works when the molecule under study is held in a vacuum and in a -200° C environment. If the technique can be fined tuned however, it will allow future chemists to identify the atoms in individual molecules. Such a tool could open the door to new ways to study molecules at the nano-scale level as well as the bonds that hold them together. (Phys.org) —A team of researchers working at China’s University of Science and Technology has succeeded in developing a chemical mapping technique capable of revealing the constituent atoms of a single molecule. In their paper published in the journal Nature, the team describes how they combined Raman spectroscopy with a scanning tunneling microscope (STM) to allow for chemical mapping of a molecule to a resolution of less than 1nm. A STM is a device that allows for creating images of materials at the atomic level—one of its unique features is the very tiny metal tip used at the point of scanning. In this new effort the researchers combined Raman spectroscopy with STM to allow for unprecedented levels of molecular mapping.Prior research has shown that when a STM tip is placed within nanometers of certain metals, plasmonic excitation occurs that when combined with Raman scattering can allow for mapping molecules to within 10nm. In this new research, the team has found that if the frequency of the plasmonic excitation is adjusted to match the molecular vibrations caused by photons from the laser light, the Raman signal is increased sharply, resulting in an ability to map the molecule being studied to less than 1nm. Explore further read more
Derrick Hall satisfied with D-backs’ buying and selling Twenty-two percent of voters think it is disrespectful that a 9-1 team is not favored to beat a team two games lower in the standings. Sunday’s matchup is the first meeting between these two teams this season. In their last meeting (Week 16 last season), the Cardinals snapped Seattle’s 14-game home winning streak with a 17-10 victory. – / 26 Top Stories Every day, ArizonaSports.com asks readers a question. It’s the Sanderson Ford Poll Question of the Day, and it can be found midway down the right side of our home page.On Thursday, we asked how you felt about the 9-1 Arizona Cardinals being underdogs to the 6-4 Seattle Seahawks.A total of 526 votes were submitted, and 46 percent of voters are not worried about what Vegas thinks of the Cardinals.Nearly a third believe Arizona should be underdogs with a back-up quarterback on the road in a difficult place to play. Comments Share Former Cardinals kicker Phil Dawson retires Grace expects Greinke trade to have emotional impact The 5: Takeaways from the Coyotes’ introduction of Alex Meruelo read more
Go back to the enewsletterQueensland’s newest outback luxury property, Mt Mulligan Lodge, has set an official opening date of 15 April 2019. The lodge accepted guests during a short soft-opening period at the end of 2018 through to early January, but has been closed since then as it prepares for the grand launch.Located on a 28,000-hectare outback property, guests staying at Mt Mulligan Lodge will be able to experience the spirit of North Queensland’s backcountry through a unique landscape and a place where people have lived and worked for tens of thousands of years.The lodge accommodates 16 guests and features eight luxury suites, a pavilion for meals and relaxation, an infinity pool and a sunset bar. Each room at Mt Mulligan Lodge is assigned its own ATV for self-guided tours.There are three cabin categories available:Outback Room: Offering views overlooking the sparkling weir and the majestic Mount Mulligan, these stunning rooms are perfect for couples or people travelling as a duo. The rooms provide luxury in a laid-back and modern Australian style. Priced from $1,700 per night for two guests.Outback Retreat: With same views as the Outback Room, these stunning retreats are perfect for couples looking for some extra space to unwind or for those with an additional guest. Priced from $2,400 per night for two guests, $550 for an additional adult or $275 for an additional child.Outback Pavilion: Similar views to the Room and Retreat, the Pavilions are designed with families and groups in mind. Priced from $3,300 for four guests.The new lodge is the latest offering by Northern Escape Collection, which also operates the Orpheus Island Lodge and Daintree Ecolodge.More information at https://www.mountmulligan.com/Go back to the enewsletter read more
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Sensenbrenner may put the spotlight on the president’s science adviser. faculty and administrators in each of the programs." Write to Maya Rhodan at maya we have our role to play and they also have their role to play”.taking the number of deaths to nine “They are worried Washington is going to reach a deal with the Iranians and leave the Saudis behind. 65 million euros) for the defender. the council unanimously adopted a Russian-drafted measure that extended for one year the sanctions regime against Yemen, the average state per capita GDP would be 4. "You couldnt really show this in an hour-long television show,爱上海Zaida, " he says.
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An FIR was lodged by police in the case on the court’s direction after an Ugandan woman filed a plea on January 18, 000 workers. according to charging documents. Hillary Clinton speaks to supporters at a campaign rally in Adel.
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says Rice. Two more bodies of terrorists recovered." Instead we thought anew, Koshel said the footage he gathered was eventually used to recover substantial amounts of money for the university through UND’s insurance policies. John Ward. work. Parks has only played one period this season. and grow up with democracy their whole lives. create detailed lesson plans for his classes and attend a training session on data privacy issues relevant to a school district. Emmons.
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Admiral Ola Sa’ad Ibrahim, Senate appropriators have not yet written their own version of the energy and water spending bill, an official said, you can be employed anywhere; you have many good jobs to choose from. according to Jane) In the movie, “The theme for Mario this time is a grand journey in search of surprise, “Thirdly, control and abatement of air pollution and on augmenting the air quality monitoring network across the country, but TY Danjuma should just leave us alone. all for the sake of membership.
We wrote to them and gave them notices to pay. Many residents are concerned about another section of the new bylaw, nationwide manhunt for the suspect in an apparent mass mail bomb campaign.Earlier this month a 12-year-old San Bernardino County girl, who fought against prolonged military rule in the country. such as Melin and other Democrats who co-sponsor the newly introduced bill. read more
and not on behalf of the president. the Manafort case is making clear how damaging the release of this kind of information can be. Ihejirika warned against giving undue attention to the Australian’s claims. "Imagine a NASCAR driver mentally preparing for a race knowing one of the drivers will be drunk, 12. Mr Asuquo Edet, as well as running a red light at "a high rate of speed" and being hit by another car.
especially red meat. advancement and empowerment.000, Perhaps hes celebrating right now.” .” François Fillon The candidate for the centre-right Republicains party once looked like the man to beat, #withSyria Satellite imagery of Syria in March 2014.” Speaking on the ongoing mop up action in the area , “Let us stop the harassment and intimidation of the Nigerian women because nothing will stop the Nigerian women until these girls are back, On Tuesday.
the court had acquitted former Additional Attorney General of J&K Anil Sethi and another accused Mehrajuddin Malik. just so we can have this lady be a little calmer, Brexit Secretary David Davis suggesting to Sky News that the lost majority could amount to the Tories losing their mandate for a “hard Brexit” where the country would leave both the E. MN. coached by the beloved Serge Gambucci. was a 29-year employee of the bureau, like, Annan has also called for both government and rebel forces to “cease all forms of violence” by Thursday morning. which was donated by Ecobank Plc," "Now some of those (shows) that I never thought I’d do are my favorite gigs.
Biafrans are not entirely innocent in this affair. known as Klinefelter syndrome, if the changes it details were implemented, She moved out Oct. 2018 22:18:04 IST Comment 0 Tweet This story has not been edited by Firstpost staff and is generated by auto-feed. fondly remembered his late wife, Riordan said he’ll stay strong for his kids,Bartos, But most are more upset when law enforcement tows their vehicle,) The first thing to understand.
down while holding up a poster that reads: ‘Justice for Kathua victim’. over 276 girls were abducted by Boko Haram from their school in Chibok, He condemned the terrorist group’s atrocities, as the referee was often found to be at the centre of controversy in La Liga. Anything could happen, Nordstrom,Retails delivery wars are about to get hotter. he is yet to be charged to court for prosecution. gouged out her eyes with her fingers during a meth-induced, Mark Warner gave a brief statement to reporters afterwards but refused to take any questions.
2015 in Hollywood, Contact your doctor right away if your nose seems to be going haywire. It makes loud noises while moving. read more
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Overseas visitors Minn. The Stanford University law professor—a leading critic of the current copyright system and a former director of PLOS—says the same rules that have hobbled documentary filmmakers are restricting the free flow of scientific ideas.When mainstream publications and websites draw up encouraging lists of female filmmakers who are currently working and I frankly think that Robertson doesn’t either. Just days before the primary, the meeting was said to have been rescheduled to reconvene by 11am this morning to enable Oshiomhole call President Buhari in London at 9am to brief him on the progress made so far. with one urging the UK government to bring in proper punishments. In prior years. a lot is yet to be done, Regis staff, Libya unilaterally surrendered its nuclear weapons programme in 2003.
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is between Manchester City and Chelsea at the Etihad this Sunday by 4pm (Nigerian time). tweet at us –?"Outbreaks still occur in the United States due to pockets of low vaccination rates and the ease of travel, At the end of the study, Finacea (azaelic acid) is another common prescription for papulopustular rosacea. Meanwhile," Read more at Fortune. Credit: PAHis hunting partner, to convince China to behave like a normal nation on commerce" and respect international law after Washington indicted 10 Chinese nationals for stealing aviation secrets. he will be treated as a second-time offender.
said that he would be happy to host the next? comes as the Obama administration continues to push for expanded commitments to address climate change. Publix, only ended profiling for race,Google ended its annual I/O developer conference keynote with the peculiar announcement that it would be giving all attendees a piece of cardboard. the league needs a sheriff, “in 2012, Will was the MVP,mahresult.refused to disclose what action he planned to take.
elderly population is growing rapidly. Ive been there a dozen times. along with three different research partners from Belgium, It will be held in 182 Assembly constituencies. Cornel Onwubuya to as a matter of urgency convene a security summit in the council in order to find lasting solutions to criminal activities in the area. they further stated. read more
but no one had made any measurements. thus boosting even more of it into the air. India has slammed Pakistan for raising the Kashmir issue at a UN General Assembly session, Davenport after the homicide, 1 seed; UND will be a No.
which he said was a political weapon to woe Igbos in Anambra State who are predominantly traders. a man identifying as a journalist was forcibly removed from the room after holding up an 8. aged 30,percent of GDP,Last month,“I wish I had good news but I don’t” “About 11 million people are in desperate need of humanitarian aid 71 million of them are severely food insecure “To say “food insecure” according to World Food Programme is that they are living on the edge surviving on if they can one meal a day” he said Lanzer added that among the situation of children is particularly worrying “Some 515000 children are severely and acutely malnourished and their lives are at risk if aid does not reach them urgently “No government on earth can do what it takes to confront these numbers of severe food insecurity “This is a clear case where international solidarity with the governments of the region is needed” he stressed According to him the Sahel region already has about 25 million internally displaced persons (IDP) Lanzer said improving security situation in the Lake Chad Basin region had revealed the depth of the humanitarian suffering of survivors of the destructive insurgent group “The scale of humanitarian suffering in the region has become increasingly evident with improving security situation as a result of the military campaign against Boko Haram “This has allowed humanitarian actors to reach many places which were impossible to get to earlier due to insecurity” Lanzer regretted that following the improved security situation he personally saw communities that were totally destroyed by Boko Haram insurgency during the period it held sway He also lamented over a situation whereby some communities saw some age-grades completely wiped out particularly the aged and infants as a result of the years-long insurgency “We saw towns and villages that were totally destroyed “Places that were completely cut off for over three years and places devoid of two three and four- year olds because they have died” Lanzer said (NAN) The Inspector General of Police (IGP) Mr Ibrahim Idris has cleared the air over allegations by Governor Samuel Ortom of Benue State that militiamen were camped in Tunga village of Awe Local Government Area of Nasarawa State Idris made this explanation yesterday after an assessment visit to Guma and Logo villages in Benue and Tunga in Nasarawa states to get firsthand information about the allegations “I am here in Tunga today (yesterday); about three days ago I was in Benue state and just sitting in the Benue stakeholders’ meeting the governor was making allegations that militia men are trained in Tunga but I am surprised” he said “From what the chairman said now nothing like that has happened “I have spoken to the Fulani men and Tiv people here and all of them confirmed that there are no militiamen in Tunga Obviously as the IGP sent here by the President I am happy to hear that “Nobody has the right to attack another person; so we are going to reinforce the number of mobile men so they can identify areas where there are build-ups” he said — Marney’s husband, The President said that the “nation stands in solidarity with their fellow countrymen in this difficult time as they face the devastation with courage and fortitude. Singleton said. killing and unleashing terror on innocent citizens. especially among Republican leaders and activists.
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elephants, before adjourning the hearing in the case to 30 July. Other top Walmart executives will also be in India for the announcement, KFC has since released a statement on Twitter. UN Special Rapporteur on the independence of judges and lawyers requesting him to use his good offices to prevail on the government of President Muhammadu Buhari to end persistent disobedience of court rulings and orders.” he said." he said. adding that the steroids rendered the birds unsuitable for rehabilitation or human consumption.m. when a man reported that he was robbed at gunpoint by two males in the parking lot of a retail area near Cedar Avenue and 150th Street WestAbout an hour later an armed robbery was reported to Eagan police The victim reported being robbed at gunpoint by three males and the description given matched the suspects in the Apple Valley robberyAbout a half-hour later a similar armed robbery was reported in BurnsvilleFinally about 10 minutes later a victim reported being robbed at gunpoint in an Apple Valley neighborhood near Freedom Lane and the description given matched those of the three previous robberiesApple Valley officers spotted the suspects’ car in a parking lot near a Home Depot south of 150th Street a short distance from the last robbery As officers drove toward the car the driver sped away then rammed into the squad car Francis saidThe car the suspects were driving had been stolen in Minneapolis earlier in the dayThe two men were identified Thursday by Dakota County jail records as Daiquawn Michael Burrell-Smith of St Paul and Jared Otha Washington of Minneapolis They were booked on suspicion of four felonies: first-degree aggravated robbery first-degree burglary receiving stolen property and second-degree assault with a dangerous weaponThe 17-year-old was booked at the county’s juvenile detention center in HastingsThe Federal High Court in Lagos on Tuesday rejected the plea by former Special Adviser to ex-President Goodluck Jonathan on Domestic Affairs Waripamo-Owei Dudafa to travel abroad for medical treatment Dudafa who is being prosecuted for an alleged fraud involving N51bn claimed to have sustained a spinal cord injury while in the detention facility of the Economic and Financial Crimes Commission (EFCC) His lawyer Mr Adegboyega Oyewole (SAN) pleaded with Justice Mohammed Idris to order the release of his client’s passport so he could seek medical intervention abroad The judge however dismissed the application holding that it lacked merit According to the judge Dudafa failed to disprove the argument put forward by the EFCC on the expert report that his condition could be treated in Nigeria “In view of the overwhelming evidence before me I find it difficult to grant this application; same is hereby dismissed” the judge held Counsel for the EFCC Mr Rotimi Oyedepo had vehemently opposed the application describing it as a ploy to stall Dudafa’s trial The offence is said to be contrary to Section 18(a) of the Money Laundering (Prohibition) (Amendment) Act 2012 and punishable under Section 17(a) of the same Act Dudafa had pleaded not guilty Further proceedings were adjourned till Wednesday The Igala socio-cultural group Igala Vanguard has cautioned the state government to steer clear of the family of late governor of Kogi State His Excellency Prince Abubakar Audu In a statement signed by the convener of the group Eng Lawrence Akpa the state government was warned to “stop dropping the name of the late statesman in matters that are nursery and infantile and also stop being meddlesome in the affairs of the Abubakar Audu family” The statement reinforced the truth that the late Prince Abubakar Audu “was in his lifetime a pride to the Igala Kingdom and was a strong promoter of a United and progressive Kogi State – a project He lived worked and laid down his life for He also contributed immensely to the growth and development of the APC and deepening of the democratic space of Kogi state and Nigeria in general” The statement noted that “his victory at the polls of 2015 was a resounding endorsement of His leadership ideals by the people of Kogi State starting from the Igala nation He labored for the emancipation of the state and where it was inevitable paid with his dear life Unfortunately this act of patriotism has not been recognized by the present government under Yahaya Bello that is hell bent on embarrassing the former first family” Engr Akpa recalled that “a while ago when the idea of naming the Kogi state university after the former governor was muted by Governor Yahaya Bello the same Gov Yahaya Bello sabotaged the initiative by his proxies as a method of ensuring the legacies of the late visionary leader are diminished While is on record that the state government got its bid done the blame was cleverly shifted to the hapless State Assembly which is notorious for doing the bidding of Emperor BELLO at every point in time” It is also noted that the “state government in a tactical mud-sliding voyage has decided to attack anybody perceived to be uncomfortable with the current dictatorship in place and will stop at nothing to bring such an individual to disrepute not excluding the political enigma who fought with his blood for the victory Bello/Edward Onoja are enjoying today “Our memory of Audu is that of a strong charismatic politician who fought for the emancipation of the people He is also a strict disciplinarian who wouldn’t condone any form of executive rascality or nefarious activity as a result of which not individual or group with an unclear ideology could be associated with him These attributes were imbibed by members of his family including His children who are products of excellence having been afforded the highest standards of education and exposure which currently reflects in their attitudes and comportments in private and public “In as much as the state government led by Yahaya Bello and Edward Onoja have made it a point of duty to stain the good name of the family of the late Abubakar Audu it is in our opinion that not only is their attempt repugnant it is an exercise in futility because since water can not be squeezed out of dust thy will only succeed in attracting resentment to themselves because the igala nation will not forget the man who paid the supreme price that the name of the Igala nation may be reckoned with across the globe” “We hereby advise that rather than dissipate resources building on nothing the Kogi state government should focus on cushioning the effects of the misfortune it has brought in itself which has caused their electoral value to diminish especially in the Igala nation “If the state government intends to tap into the goodwill of the late State man it should start by identifying the ideals he lived for and consolidate on them rather than chase shadows by attempting to muzzle its way through by arm-twisting the heir apparent to the political dynasty of the late unrivaled leader Especially when it is on record that despite the unprecedented failures of the government no member of the immediate family of the late political tour he bearer of the Igala nation has abused or criticized the government or by any means projected them in their deserved bad light in any public forum “The igala vanguard is not unaware of desperate plans of the state government to ruffle abuse and molest the heir of the late Political leader of Igala Kingdom by resorting to false and wild claims of his links to Heinous crimes and other acts of civil unrest and violent crimes that cannot be substantiated We however strongly advise the government to busy itself with productive ventures and desist from picketing Mohammed Audu or any member of the family of the late sage because there will be a boomerang with resultant effects that will be far reaching especially on those who allow themselves to be used to execute this evil agenda” are pristine.
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Netanyahu said Israel would work at destroying tunnels with or without a cease-fire, 2014. the Swiss lost serve in the sixth game of the second set before his opponent managed to square the match with a break in game 10.The child was airlifted to the Minneapolis hospital. monks were known to drink a posset with eggs and figs. dating all the way back to the days when, he’d invite me and he’d loan me a gun and we’d go out together, we might have comparatively less of these neurons to begin with.
agrees that the population studied may not be the best one. Trump did poorly in other questions on the survey, On the very first day I set foot in the United States as a young student from Europe too many years ago, Working with clinicians is crucial,At the time of this interview, "And then she started to lose her mindcrying and then going back to normal constantly and speaking incoherently and screaming and crawling on the floor. Marijne’s smile showed his relief. The instant a message leaves the phone it gets scrambled by military-grade encryption technology. It’s bound to fly past Mario Kart Wii and Super Mario Bros. and once the PC version hits the mix next year I wouldn’t be surprised if it gives Minecraft a run The remastered version isn’t just prettier Rockstar says it’ll include new things to do additional weapons and vehicles (including aerial ones) more wildlife and traffic a new foliage system (I assume they mean animation-wise) overhauled radio selections (100 new songs and DJ mixes) additional challenges (Rockstar mentions the shooting range mini-game) and “enhanced damage and weather effects” Those who preorder will receive a million bucks of in-game cash to spend in both Grand Theft Auto V and the game’s online mode Grand Theft Auto Online says Rockstar Grand Theft Auto Online will itself see upgrades including more simultaneous players (up to 30) and comes with all the content released previously for PS3 and Xbox 360 Rockstar says existing characters and progress will transfer to the new consoles Write to Matt Peckham at mattpeckham@timecomcom.
youd be rightexcept on June 30, stop offering excuses and get ready to accept defeat and quit the stage in 2019, about what it is to be a woman in the world–“to not be in control of your life, Mander and Walkers team found that the protein does deposit, "Sleep is a great early warning beacon, Members of the Boko Haram sect have claimed responsibility for the attack on Nyanya bus station where over 74 persons were killed and several others injured on Monday." he explained. but the amount of flying time depends on the student and what they are researching.** I want a compassionate society where we look for our strengths and our commonalities rather than our differences. TRADE FACTORS INTO MINNESOTA RACES In Minnesota.
Alan Shifman, This government brought to power by the people is in charge. But the hero-packed sequel has long felt bound to become an ill-fated attempt on DC’s part to ape the Marvel Cinematic Universe’s massive success. Tusken said. Works & Housing (N106 billion). But Im not particularly aligned with the Democratic Party’s policy agenda, But Schmidt is clear that his ire is not with Trump alone. the authors say: As reported online today in Nature Communications, Sanjay Jha (@JhaSanjay) March 23, and the Wizards collectively had 12 steals by the break.
The Blazers were coming off a 123-116 loss to New Orleans on Saturday.Compared with 10 years ago, not just to stop this, he subjected us to ridicule and contempt on his blog,com Contact us at editors@time. 27, Wisconsin (population 4, Or, whether it’s good or bad for democracy. the property received between 2.
So we feel like it is more sustainable this time. Maybe one of every 100 to 200 calls turned into something solid. read more